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Synthesis 1989; 1989(11): 814-817
DOI: 10.1055/s-1989-27399
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Chiral Cyclopentadienes

Katerina Matcheva* , Marion Beckmann, Dietmar Schomburg, Ekkehard Winterfeldt
  • *Institut für Organische Chemie der Universität Hannover, Schneiderberg 1 B, D-3000 Hannover 1, Federal Republic of Germany
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Publikationsdatum:
02. Mai 2002 (online)

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Efficient syntheses of enantiomerically pure cyclopentadienes which undergo stereoselective and regioselective high pressure cycloadditions with nonsymmetric dienophiles are reported. As these compounds show a quite high chemical as well as thermal stability they are useful as templates in the generation of pure enantiomers by diastereoselective adduct transformation and subsequent retro-Diels-Alder reaction.