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Synthesis 1989; 1989(3): 207-208
DOI: 10.1055/s-1989-27200
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Synthesis of Tetrachloro- and Tetrabromotetrathiafulvalene

M. Jørgensen* , K. Bechgaard
  • *Department of General and Organic Chernistry, University of Copenhagen, The H. C. Ørsted Institute, DK-2100 Copenhagen, Denmark
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Publikationsdatum:
17. September 2002 (online)

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Tetrathiafulvalene (TTF, 1) is tetralithiated with phenyllithium, and the intermediate is halogenated in an unusual reaction, to give the new donors tetrachloro- and tetrabromotetrathiafulvalene (TClTTF, 2) and (TBrTTF, 3).