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Synthesis 1989; 1989(2): 121-123
DOI: 10.1055/s-1989-27167
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Synthesis of Trialkylsilylated α-Hydroperoxy Aldehydes and Ketones via Ozonolysis of Protected Allylic Hydroperoxides

Waldemar Adam* , Luiz H. Catalani, Chantu R. Saha-Möller, Bernd Will
  • *Institute of Organic Chemistry, University of Würzburg, D-8700 Würzburg, Federal Republic of Germany
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Publication Date:
17 September 2002 (online)

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α-Silylperoxy aldehydes and ketones 3 have been prepared by ozonolysis of silyl-protected allylic hydroperoxides, followed by subsequent reduction of the latter with dimethyl sulfide. Deprotection of silylperoxy aldehydes 3a-c with fluoride ion led to decomposition with chemiluminescence.