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Synthesis 1987; 1987(3): 318-320
DOI: 10.1055/s-1987-27933
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One-Pot Synthesis of Substituted Homoallylic Alcohols (3-Alkenols) and 1-Deuterio-3-alkenols; II.1 Extension to Ketone Enolates

José Barluenga* , Flora Alvarez, José M. Concellón, Pablo Bernad, Miguel Yus
  • *Departamento de Química Orgánica, Facultad de Química, Universidad de Oviedo, E-33071 Oviedo, Spain
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Publication Date:
12 September 2002 (online)

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The reaction of different lithium ketone enolates with α-chloro carbonyl compounds followed by in situ reduction with lithium aluminium hydride or deuteride and final lithiation with ltihium powder leads to the corresponding homoallylic or 1-deuterio homoallylic alcohols in a regioselective manner.