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Synthesis 1986; 1986(9): 776-777
DOI: 10.1055/s-1986-31776
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Desulfurizative Germylation: Synthesis and Reaction of Allyl- and Allenylgermanes

Hiroshi Sano* , Yoshiyuki Miyazaki, Makoto Okawara, Yoshio Ueno
  • *Research Laboratory of Resources Utilization, Tokyo Institute of Technology, Nagatsuta, Midoriku, Yokohama 227, Japan
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Publication Date:
20 August 2002 (online)

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Allyl- and allenylgermanes were obtained by the reaction of allyl- or propargyl sulfur compounds with triphenylgermane in the presence of a radical initiator. Allylgermanes are as effective in the allylation of aldehydes as allylsilanes or stannanes.

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