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Synthesis 1985; 1985(8): 743-748
DOI: 10.1055/s-1985-31330
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α-Secondary Dialkylallylamines from Aminonitriles via the Bruylants Reaction

Hubertus AHLBRECHT* , Horst DOLLINGER
  • *Fachbereich Chemie der Universität Gießen, Institut für Organische Chemie, Heinrich-Buff-Ring 58, D-6300 Gießen, Federal Republic of Germany
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Publication Date:
17 September 2002 (online)

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The pracitally unknown α-secondary allylamines 1 have been synthesised in good to very good yields by reaction of allylaminonitriles 7 with Grignard reagents. The reaction is regio- and stereoselective and can also be run with α-aminonitriles 9 and vinyl Grignard reagents.