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Synthesis 2021; 53(04): 713-722
DOI: 10.1055/s-0040-1707293
DOI: 10.1055/s-0040-1707293
paper
A Three-Step Synthesis of 1,7-Diazaperylene and Derivatives
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Abstract
1,7-Diazaperylene and various derivatives were synthesised in an upscaleable route from 1,5-diaminoanthraquinone and its Meerwein reaction with acrylonitrile and subsequent cyclisation with ammonia. The application of tert-butyl alcohol as the solvent led to a significant improvement in the Meerwein reaction.
Supporting Information
- Supporting information for this article is available online at https://doi.org/10.1055/s-0040-1707293.
- Supporting Information
Publication History
Received: 30 May 2020
Accepted after revision: 31 August 2020
Article published online:
27 October 2020
© 2020. Thieme. All rights reserved
Georg Thieme Verlag KG
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