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Synthesis 2019; 51(22): 4170-4182
DOI: 10.1055/s-0039-1690618
DOI: 10.1055/s-0039-1690618
paper
Efficient Synthesis of Diverse 5-Thio- or 5-Selenotriazoles: One-Pot Multicomponent Reaction from Elemental Sulfur or Selenium
Weitere Informationen
Publikationsverlauf
Received: 17. Mai 2019
Accepted after revision: 06. August 2019
Publikationsdatum:
21. August 2019 (online)
Abstract
A sequential multistep reaction toward 5-thio- or 5-selenotriazoles has been established by generation of both copper(I) triazolides and sulfenylating or selenylating agents in situ, starting from elemental sulfur or selenium. This reaction features mild conditions, readily available and broad-scope substrates, good functional group compatibility, high efficiency and regioselectivity, easy operation, and ligand-free CuI.
Supporting Information
- Supporting information for this article is available online at https://doi.org/10.1055/s-0039-1690618.
- Supporting Information
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