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Synthesis 2019; 51(10): 2214-2220
DOI: 10.1055/s-0037-1612249
DOI: 10.1055/s-0037-1612249
paper
Facile Synthesis of Hydroxy-Substituted Thiacrown Ethers via Nucleophilic Ring Opening of Epoxides
Authors acknowledge financial support from National Science Center in Cracow (Poland) (Preludium 9 Grant No. UMO-2015/17/N/ST5/03028).Weitere Informationen
Publikationsverlauf
Received: 05. Dezember 2018
Accepted after revision: 21. Januar 2019
Publikationsdatum:
25. Februar 2019 (online)
Abstract
The title thiacrown ethers were prepared in a one-step procedure to give a series of unique macrocycles possessing two unsubstituted hydroxy groups that can be easily functionalized. In addition, epoxides and macrocycles derived from Cookson’s birdcage diketone, were prepared. The nucleophilic ring opening of epoxides synthesis can be classified in the frame of click chemistry. Surprisingly, some of the prepared allyl substituted polyglycols as well as bis-epoxides, especially sulfur analogues, were prepared for the first time.
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