Synlett 2019; 30(18): 2035-2040
DOI: 10.1055/s-0037-1611903
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© Georg Thieme Verlag Stuttgart · New York

Recent Progress in the Copper-Catalyzed Cascade Cyclization Involving Intramolecular Hydroamination of Terminal Alkynes

Tong-De Tan
a   State Key Laboratory of Physical Chemistry of Solid Surfaces & The Key Laboratory for Chemical Biology of Fujian Province, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, P. R. of China   Email: longwuye@xmu.edu.cn
,
Yang-Bo Chen
a   State Key Laboratory of Physical Chemistry of Solid Surfaces & The Key Laboratory for Chemical Biology of Fujian Province, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, P. R. of China   Email: longwuye@xmu.edu.cn
,
Xin-Yang Fan
a   State Key Laboratory of Physical Chemistry of Solid Surfaces & The Key Laboratory for Chemical Biology of Fujian Province, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, P. R. of China   Email: longwuye@xmu.edu.cn
,
Long-Wu Ye
a   State Key Laboratory of Physical Chemistry of Solid Surfaces & The Key Laboratory for Chemical Biology of Fujian Province, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, P. R. of China   Email: longwuye@xmu.edu.cn
b   State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, P. R. of China
› Author Affiliations
We are grateful for the financial support from the National Natural Science Foundation of China (21622204 and 21772161), the President Research Funds from Xiamen University (20720180036), the Science & Technology Cooperation Program of Xiamen (3502Z20183015), PCSIRT, and NFFTBS (J1310024).
Further Information

Publication History

Received: 24 June 2019

Accepted after revision: 15 July 2019

Publication Date:
30 July 2019 (online)


‡ These authors contributed equally to this work.

Abstract

Transition-metal-catalyzed cascade cyclization initiated by intramolecular alkyne hydroamination has received considerable attention over the past decade and has been widely used in the rapid construction of a diverse array of valuable complex N-heterocycles. Recent progress in this area is reviewed with an emphasis on the cheap and environmentally benign copper-catalyzed cascade cyclization of terminal alkynes.

 
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