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Synthesis 2019; 51(17): 3305-3312
DOI: 10.1055/s-0037-1611824
DOI: 10.1055/s-0037-1611824
paper
New Zinc Catalyst for Hydrosilylation of Carbonyl Compounds
This research was supported by the Natural Sciences and Engineering Research Council of Canada (Discovery Grant, 2017-05231 to G.I.N.).Weitere Informationen
Publikationsverlauf
Received: 07. März 2019
Accepted after revision: 18. April 2019
Publikationsdatum:
07. Mai 2019 (online)
Abstract
A new zinc complex was synthesized and applied in the catalytic hydrosilylation of carbonyl compounds. Optimization of the reaction conditions showed that the presence a substoichiometric amount of methanol accelerates the process significantly. The reaction can proceed at very low catalyst load (down to 0.1 mol%) under mild reaction conditions. The reaction tolerates the presence of C=C bonds, and thus can be useful for the synthesis of allylic alcohols from α,β-unsaturated aldehydes and ketones.
Supporting Information
- Supporting information for this article is available online at https://doi.org/10.1055/s-0037-1611824.
- Supporting Information
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