Synthesis 2019; 51(16): 3077-3084
DOI: 10.1055/s-0037-1611799
paper
© Georg Thieme Verlag Stuttgart · New York

Palladium-Catalyzed C(sp2)−H Olefination/Annulation Cascades of Aryl Carboxamides Assisted by N,S-Bidentate Auxiliary

Ling Li
,
Xing-Guo Zhang
,
Xiao-Hong Zhang*
College of Chemistry and Materials Engineering, Wenzhou University, Wenzhou 325035, P. R. of China   Email: kamenzxh@wzu.edu.cn
› Author Affiliations
We thank the National Natural Science Foundation of China (No. 21302144) for financial support.
Further Information

Publication History

Received: 27 January 2019

Accepted after revision: 25 March 2019

Publication Date:
25 April 2019 (online)


Abstract

A palladium(II)-catalyzed olefination/annulation of aryl carboxamides, assisted by an N, S-bidentate auxiliary, with methyl acrylate is described. Various carboxamides with a number of functional groups were compatible with this reaction to afford, regioselectively and in moderate yield, (E)-3-methyleneisoindolin-1-one derivatives bearing an alkyl(aryl)thio group.

Supporting Information

 
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