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Synthesis 2018; 50(20): 4008-4018
DOI: 10.1055/s-0037-1610241
DOI: 10.1055/s-0037-1610241
short review
Stereoselective Reactions of ortho-Quinone Methide and ortho-Quinone Methide Imines and Their Utility in Natural Product Synthesis
C.D.T.N. thanks Syngenta (Pharmacat consortium) for a Ph.D. studentship.Further Information
Publication History
Received: 19 July 2018
Accepted: 19 July 2018
Publication Date:
14 August 2018 (online)
‡ These authors contributed equally to this review.
Abstract
Herein presented is a review of the reactivity and synthetic utility of ortho-quinone methides and ortho-quinone methide imines. These versatile intermediates have received significant attention in the literature and new methods for their preparation and reaction as well as recent applications in total synthesis are discussed.
1 Introduction
2 Conjugate Addition Reactions
3 Concerted Cycloaddition Reactions
4 Stepwise Addition Reactions
5 Applications in Total Synthesis
6 Conclusion
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