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Synthesis 2018; 50(04): 711-722
DOI: 10.1055/s-0036-1589155
DOI: 10.1055/s-0036-1589155
short review
tert-Butyl Nitrite (TBN) as a Versatile Reagent in Organic Synthesis
We thank the Natural Science Foundation of China (NSFC, No. 21362030 and 21562038) for supporting our research.Further Information
Publication History
Received: 27 October 2017
Accepted after revision: 22 November 2017
Publication Date:
14 December 2017 (online)
Abstract
tert-Butyl nitrite (TBN) is an important metal-free reagent that is widely applied in various organic transformations. Besides its traditional applications in nitrosation and diazotization, its ability to activate molecular oxygen to enable the initiation of radical reactions, including nitration, oximation, oxidation, and so on, has attracted extensively attention in the past decade. This review highlights recent advances in this field to promote further exploration of this versatile compound.
1 Introduction
2 Reactions Involving TBN
2.1 Nitrosation
2.2 Oximation
2.3 Diazotization
2.4 Nitration
2.5 Oxidation
2.6 Other Reactions
3 Conclusion and Perspective
-
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