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Synthesis 2017; 49(08): 1796-1807
DOI: 10.1055/s-0036-1588686
DOI: 10.1055/s-0036-1588686
paper
Grubbs–Hoveyda Second-Generation Catalysts Activated by the Introduction of a Light Fluorous Tag onto the Bidentate Ligands
Further Information
Publication History
Received: 16 November 2016
Accepted after revision: 13 December 2016
Publication Date:
11 January 2017 (online)


Abstract
Various novel Grubbs–Hoveyda second-generation catalysts activated by a fluorous tag on the ligands were prepared. The catalyst bearing the 1-naphthyl group on the bidentate ligand exhibited the highest catalytic activity among the studied catalysts for the ring-closing-metathesis reaction of diethyl 2-allyl-2-(2-methylallyl)malonate.
Supporting Information
- Supporting information for this article is available online at http://dx.doi.org/10.1055/s-0036-1588686.
- Supporting Information