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DOI: 10.1055/s-0036-1588644
Thieme Chemistry Journals Awardees – Where Are They Now?
What’s Golden: Recent Advances in Organic Transformations Using Photoredox Gold Catalysis
Publikationsverlauf
Received: 09. September 2016
Accepted after revision: 12. Oktober 2016
Publikationsdatum:
17. November 2016 (online)
![](https://www.thieme-connect.de/media/synlett/201703/lookinside/thumbnails/st-2016-a0604-a_10-1055_s-0036-1588644-1.jpg)
Abstract
Light-mediated photoredox transformations have become commonplace in contemporary catalysis research and design. Excited-state redox catalysts trigger photoinduced electron transfers (PET) through oxidative or reductive quenching modes, allowing access to one-electron variations of classic radical reactions and the discovery of new transformations in organic chemistry. Herein, the use of Au-based photoredox catalysts containing powerful redox properties along with the emergence of dual catalyzed organic transformations involving photoredox catalysis and Au complexes for the Au(I)/Au(III) redox couple without use of stoichiometric oxidants will be discussed.
1 Principles of Photochemistry and Gold
2 Photoredox Transformations with Dimeric Gold Complexes
3 Dual Catalysis Involving Au(I)/Au(III) Redox Cycles
4 Concluding Remarks
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For seminal description, characterization and theoretical studies of aurophilic interactions in polynuclear Au(I) complexes:
For seminal work:
For β-hydride elimination processes with Au-based complexes: