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Synlett 2017; 28(18): 2453-2459
DOI: 10.1055/s-0036-1588488
DOI: 10.1055/s-0036-1588488
cluster
(HMe2SiCH2)2: A Useful Reagent for B(C6F5)3-Catalyzed Reduction–Lactonization of Keto Acids: Concise Syntheses of (–)-cis-Whisky and (–)-cis-Cognac Lactones
We are grateful for financial support from the National Natural Science Foundation of China (21290180, 21622202, 21502125).Further Information
Publication History
Received: 23 April 2017
Accepted after revision: 10 June 2017
Publication Date:
19 July 2017 (online)
Published as part of the Cluster Silicon in Synthesis and Catalysis
Abstract
(HMe2SiCH2)2 has been utilized as a useful reagent for B(C6F5)3-catalyzed reduction–lactonization of keto acids to synthesize γ- and δ-lactones. The process led concisely to (–)-cis-whisky and (–)-cis-cognac lactones in respective overall yields of 32% and 36%.
Supporting Information
- Supporting information for this article is available online at https://doi.org/10.1055/s-0036-1588488.
- Supporting Information
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For selected reviews, see:
For selected reviews, see:
For selected reviews, see:
For selected seminal works on B(C6F5)3, see:
For related works, see: