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Synthesis 2016; 48(18): 3031-3041
DOI: 10.1055/s-0035-1562515
DOI: 10.1055/s-0035-1562515
psp
Practical Synthetic Procedures for the Iron-Catalyzed Intermolecular Olefin Aminohydroxylation Using Functionalized Hydroxylamines
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Publikationsverlauf
Received: 02. Juni 2016
Accepted after revision: 06. Juni 2016
Publikationsdatum:
25. Juli 2016 (online)


‡ These authors contributed equally to this study.
Abstract
A set of practical synthetic procedures for the iron-catalyzed intermolecular olefin aminohydroxylation reactions in gram scale is reported. In these transformations, a bench-stable functionalized hydroxylamine is applied as the amination reagent. This method is compatible with a broad range of synthetically valuable olefins including those that are incompatible with the existing aminohydroxylation methods. It also provides valuable amino alcohol building blocks with regio- and stereochemical arrays that are complementary to known methods.
Supporting Information
- Supporting information for this article is available online at http://dx.doi.org/10.1055/s-0035-1562515.
- Supporting Information