Synlett 2016; 27(16): 2293-2300
DOI: 10.1055/s-0035-1562506
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© Georg Thieme Verlag Stuttgart · New York

Phosphaphenalenes: An Evolution of the Phosphorus Heterocycles

Philip Hindenberg
Organisch-Chemisches Institut, Ruprecht-Karls-Universität Heidelberg, Im Neuenheimer Feld 270, 69120 Heidelberg, Germany   Email: carlos.romero.nieto@oci.uni-heidelberg.de
,
Carlos Romero-Nieto*
Organisch-Chemisches Institut, Ruprecht-Karls-Universität Heidelberg, Im Neuenheimer Feld 270, 69120 Heidelberg, Germany   Email: carlos.romero.nieto@oci.uni-heidelberg.de
› Author Affiliations
Further Information

Publication History

Received: 09 May 2016

Accepted after revision: 30 May 2016

Publication Date:
18 July 2016 (online)


Abstract

The incorporation of phosphorus atoms into cyclic conjugated structures provides heterocycles with unique properties. Although the first phosphorus heterocycles date from the late 1950’s, their application in materials science is relatively recent. Extensive research efforts are being currently invested in the discovery of novel phosphorus architectures that could open up new horizons in materials science. In that context, we provide herein a comprehensive overview about the development of the phosphorus heterocycles, highlighting our recent contribution to the field; that is, a new synthetic protocol to access novel fused six-membered heterocycles. This method enables the preparation of highly versatile phosphaphenalene derivatives.

 
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