Synlett 2016; 27(06): 821-830
DOI: 10.1055/s-0035-1560550
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© Georg Thieme Verlag Stuttgart · New York

Exploiting 3,3-Difluoropropenes for the Synthesis of Monofluoroalkenes

Myriam Drouin
,
Jean-Denys Hamel
,
Jean-François Paquin*
Further Information

Publication History

Received: 28 September 2015

Accepted after revision: 26 October 2015

Publication Date:
28 December 2015 (online)


Abstract

In this account, we summarize our work on the synthesis of monofluoroalkenes starting from difluoropropenes.

1 Introduction

2 Metal-Catalyzed Transformations of 3,3-Difluoropropenes

2.1 Palladium Catalysis

2.2 Platinum Catalysis

3 Metal-Free Reactions

3.1 Organolithium Reagents

3.2 Lithium Amides

4 Conclusions

 
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