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Synthesis 2016; 48(17): 2816-2822
DOI: 10.1055/s-0035-1560439
DOI: 10.1055/s-0035-1560439
special topic
Nickel-Catalyzed Reductive Carboxylation of Cyclopropyl Motifs with Carbon Dioxide
Further Information
Publication History
Received: 09 March 2016
Accepted: 13 March 2016
Publication Date:
11 April 2016 (online)
![](https://www.thieme-connect.de/media/synthesis/201617/lookinside/thumbnails/ss-2016-z0171-op_10-1055_s-0035-1560439-1.jpg)
Abstract
A nickel-catalyzed reductive carboxylation technique for the synthesis of cyclopropanecarboxylic acids has been developed. This user-friendly and mild transformation operates at atmospheric pressure of carbon dioxide and utilizes either organic halides or alkene precursors, thus representing the first example of catalytic reductive carboxylation of secondary counterparts lacking adjacent π-components.
Supporting Information
- Supporting information for this article is available online at http://dx.doi.org/10.1055/s-0035-1560439.
- Supporting Information
Primary Data
- Primary data for this article are available online at http://www.thieme-connect.com/products/ejournals/journal/10.1055/s-00000084 and can be cited using the following DOI: 10.4125/pd0076th.
- Primary Data
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