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Synlett 2016; 27(02): 203-214
DOI: 10.1055/s-0035-1560213
DOI: 10.1055/s-0035-1560213
account
Developments in Externally Regulated Ring-Opening Metathesis Polymerization
Further Information
Publication History
Received: 05 June 2015
Accepted after revision: 10 August 2015
Publication Date:
20 October 2015 (online)
Abstract
This account details externally regulated ring-opening metathesis polymerization (ROMP) methods. Various external stimuli are discussed which collectively span chemical, thermal, photochemical, electrochemical, and mechanical modes of catalyst activation. Specific attention is also given to the recent development of a metal-free approach to ROMP that includes electro-organic and photoredox-mediated systems.
1 Introduction
2 Externally Regulated Ring-Opening Metathesis Polymerization
2.1 Acid-Activated Ring-Opening Metathesis Polymerization Catalysts
2.2 Thermally Activated Ring-Opening Metathesis Polymerization Catalysts
2.3 Mechanically Activated Ring-Opening Metathesis Polymerization Catalysts
2.4 Photochemically Activated Ring-Opening Metathesis Polymerization Catalysts
2.5 Redox-Activated Ring-Opening Metathesis Polymerization Catalysts
3 Metal-Free Ring-Opening Metathesis Polymerization
3.1 Electro-organic Ring-Opening Metathesis Polymerization
3.2 Photoredox-Mediated Ring-Opening Metathesis Polymerization
4 Conclusions and Outlook
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