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Synthesis 2015; 47(21): 3309-3314
DOI: 10.1055/s-0034-1380448
DOI: 10.1055/s-0034-1380448
paper
Synthesis of Malonates from 3-Halopropynoates, Alcohols, and Water Using DABCO
Further Information
Publication History
Received: 28 March 2015
Accepted after revision: 04 May 2015
Publication Date:
24 July 2015 (online)
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Abstract
A new 1,4-diazabicyclo[2.2.2]octane (DABCO) mediated synthesis of malonates from 3-halopropynoates, alcohols, and water is presented. This method proceeds under mild and metal-free conditions, and represents a new straightforward access to 1,3-dicarbonyl compounds.
Supporting Information
- Supporting information for this article is available online at http://dx.doi.org/10.1055/s-0034-1380448.
- Supporting Information
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