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Synthesis 2015; 47(14): 2081-2087
DOI: 10.1055/s-0034-1379910
DOI: 10.1055/s-0034-1379910
paper
(NH4)2S2O8-Mediated Diiodination of Alkynes with Iodide in Water: Stereospecific Synthesis of (E)-Diiodoalkenes
Further Information
Publication History
Received: 10 February 2015
Accepted after revision: 18 March 2015
Publication Date:
22 April 2015 (online)
Abstract
A new approach to the stereospecific diiodination of alkynes under mild conditions has been developed. This protocol employs ammonium persulfate as an oxidant and iodide as an iodine source, and provides a highly efficient and general method for the preparation of a broad range of (E)-diiodoalkenes in water.
Supporting Information
- Supporting information for this article is available online at http://dx.doi.org/10.1055/s-0034-1379910.
- Supporting Information
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For selective application of vic-dihaloalkene, see:
For selective application of gem-dihaloalkene, see:
For some selected examples, see:
For reviews, see: