Synlett 2014; 25(13): 1939-1940
DOI: 10.1055/s-0034-1378326
spotlight
© Georg Thieme Verlag Stuttgart · New York

New Uses for Indium(III) Chloride

Rosana Helena C. N. Freitas
LASSBio, B16, CCS, Federal University of Rio de Janeiro, 21941-902, Rio de Janeiro, Brazil   Email: rosanahf@iq.ufrj.br
› Author Affiliations
Further Information

Publication History

Publication Date:
01 July 2014 (online)

Introduction

Indium(III) chloride (InCl3) is an inexpensive, commercially available, easy-to-handle, air- and water-stable Lewis acid with moderate toxicity. It shows a high tolerance to most functional groups including oxygen and ­nitrogen functionalities.[1] Additionally, InCl3 is very attractive for green-chemistry reactions due to its recyclability.[2] Therefore, InCl3 has been described as a catalyst for various reactions, especially multicomponent reactions (MCR),[3] as given below.

 
  • References


    • For examples see:
    • 1a Manian RD. R.S, Jayashankaran J, Raghunathan R. Tetrahedron Lett. 2007; 48: 4139
    • 1b Mukherjee D, Sarkar SK, Chowdhury US, Taneja SC. Tetrahedron Lett. 2007; 48: 663
    • 1c Kumar CV. S, Puranik VG, Ramana CV. Chem. Eur. J. 2012; 18: 9601
    • 1d Lingam KA. P, Shanmugam P, Mandal AB. Synlett 2012; 23: 2903

      For examples see:
    • 2a Kantam ML, Roy M, Roy S, Subhas MS, Sreedhar B, Choudary BM, De RL. J. Mol. Catal. A: Chem. 2007; 265: 244
    • 2b Sun G, Sun H, Wang Z, Zhou M.-M. Synlett 2008; 1096

      For examples see:
    • 3a Liu X.-t, Huang L, Zheng F.-j, Zhan Z.-p. Adv. Synth. Catal. 2008; 350: 2778
    • 3b Lakshmi NV, Kiruthika SE, Perumal PT. Synlett 2011; 10: 1389
    • 3c Acharya C, Dey S, Jaisankar P. Tetrahedron Lett. 2012; 53: 5548
    • 3d Khurana JM, Chaudhary A, Nand B, Lumb A. Tetrahedron Lett. 2012; 53: 3018
    • 3e Majumdar KC, Ghosh D, Ponra S. Synthesis 2013; 45: 2983
  • 4 Dey S, Nandi D, Pradhan PK, Giri VS, Jaisankar P. Tetrahedron Lett. 2007; 48: 2573
  • 5 Suresh R, Muthusubramanian S, Nagaraj M, Manickam G. Tetrahedron Lett. 2013; 54: 1779
  • 6 Nandi GC, Samai S, Singh MS. Synlett 2010; 7: 1133
  • 7 Lin M, Hao L, Liu X.-t, Chen Q.-z, Wu F, Yan P, Xu S.-x, Chen X.-l, Wen J.-j, Zhan Z.-p. Synlett 2011; 665
  • 8 Prajapati D, Sarma R, Bhuyan D, Hu W. Synlett 2011; 627
  • 9 Lee O.-Y, Law K.-L, Ho C.-Y, Yang D. J. Org. Chem. 2008; 73: 8829
  • 10 Xing P, Zang W, Huang Z.-g, Zhan Y.-x, Zhu C.-j, Jiang B. Synlett 2012; 23: 2269
  • 11 Saavedra JZ, Resendez A, Rovira A, Eagon S, Haddenham D, Singaram B. J. Org. Chem. 2012; 77: 221
  • 12 Liu P, Pan Y.-m, Hu K, Huang X.-c, Liang Y, Wang H.-s. Tetrahedron 2013; 69: 7925
  • 13 Mosset P, Grée R. Synlett 2013; 24: 1142