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Synthesis 2014; 46(12): 1639-1647
DOI: 10.1055/s-0033-1341154
DOI: 10.1055/s-0033-1341154
paper
Iterative Iodocyclization: Total Synthesis of Polyrhacitide B
Further Information
Publication History
Received: 09 February 2014
Accepted after revision: 14 March 2014
Publication Date:
11 April 2014 (online)
Abstract
A highly stereoselective total synthesis of polyrhacitide B is reported. Key reactions are an iodocyclization protocol developed in our group, the Maruoka asymmetric allylation, the Bartlett–Smith iodocarbonate cyclization, and iodolactonization.
Key words
natural products - total synthesis - iodine-catalyzed cyclization - asymmetric allylation - iodocarbonate cyclization - oxidative cleavageSupporting Information
- for this article is available online at http://www.thieme-connect.com/ejournals/toc/synthesis.
- Supporting Information
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