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Synlett 2014; 25(07): 899-904
DOI: 10.1055/s-0033-1340625
DOI: 10.1055/s-0033-1340625
synpacts
Oxidative Allylic Amination Reactions of Unactivated Olefins – At the Frontiers of Palladium and Selenium Catalysis
Further Information
Publication History
Received: 16 October 2013
Accepted after revision: 11 December 2013
Publication Date:
24 January 2014 (online)
![](https://www.thieme-connect.de/media/synlett/201407/lookinside/thumbnails/10.1055-s-0033-1340625-1.jpg)
Abstract
The direct oxidative conversion of simple, nonactivated alkenes into allylic amine derivatives represents a profound challenge to contemporary chemical synthesis. This article provides an overview on recent methodological developments and applications in the realm of modern palladium- and selenium-catalyzed oxidative allylic amination reactions.
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For selected review articles on C–H nitrogenations, see:
For selected review articles, see:
For an example of an NHC ligand, see:
For reviews, see:
For representative racemic variants of this approach, see:
For recent selected examples of pharmacological studies on γ4-amino acids, see: