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Synlett 2014; 25(14): 1946-1952
DOI: 10.1055/s-0033-1340194
DOI: 10.1055/s-0033-1340194
synpacts
Hydrodefluorination of Perfluoroarenes Meets Visible Light Photocatalysis
Weitere Informationen
Publikationsverlauf
Received: 09. April 2014
Accepted after revision: 30. April 2014
Publikationsdatum:
23. Mai 2014 (online)


Abstract
Partially fluorinated arenes are increasingly found in pharmaceuticals, agrochemicals and materials. While interest in these molecules is high, the number of available methods for their syntheses is severely limited. While installation of a single fluorine is achievable, installation of several fluorines represents a significant challenge. Approaching this synthetic problem from the opposite direction has been more fruitful. Specifically, by subjecting perfluorinated arenes to selective hydrodefluorination the desired molecules can be obtained. Herein, the advancement of this approach is discussed.