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Synthesis 2013; 45(24): 3387-3391
DOI: 10.1055/s-0033-1339929
DOI: 10.1055/s-0033-1339929
paper
Copper/Imidazolium/TEMPO-Catalyzed Aerobic Oxidation of Benzylic Alcohols in Water
Further Information
Publication History
Received: 30 July 2013
Accepted after revision: 21 September 2013
Publication Date:
09 October 2013 (online)
Abstract
Various imidazolium salts bearing hydrophilic groups were prepared that reacted with copper powder to afford water-soluble copper complexes of N-heterocyclic carbenes. These copper complexes can catalyze the selective oxidation of benzyl alcohols to the corresponding aldehydes in water at room temperature without the need for a base.
Supporting Information
- for this article is available online at http://www.thieme-connect.com/ejournals/toc/synthesis.
- Supporting Information
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