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Synthesis 2013; 45(20): 2913-2918
DOI: 10.1055/s-0033-1339498
DOI: 10.1055/s-0033-1339498
paper
Synthesis of Diarylated Aromatic Hydrocarbons by Dehydroxylation of Diols Using the Titanium(IV) Chloride and Triethylamine Reagent System
Further Information
Publication History
Received: 02 May 2013
Accepted after revision: 11 July 2013
Publication Date:
14 August 2013 (online)
![](https://www.thieme-connect.de/media/synthesis/201320/lookinside/thumbnails/10.1055-s-0033-1339498-1.jpg)
Abstract
1,2-Diarylacenaphthylene, 9,10-diarylphenanthrene and 9,10-diarylanthracene derivatives were obtained in good yields (61–92%) in short reaction times (5–30 min) from the corresponding diols with the titanium(III) reagent prepared in situ using the TiCl4/Et3N reagent system in dichloromethane at 25 °C.
Key words
polycyclic aromatic hydrocarbons - dehydroxylation - diols - titanium tetrachloride - triethylamineSupporting Information
- for this article is available online at http://www.thieme-connect.com/ejournals/toc/synthesis. Included are characterization data and copies of the 1H and 13C NMR spectra for all products, as well as crystallographic data for compound 2f.
- Supporting Information
-
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