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Synthesis 2014; 46(14): 1871-1880
DOI: 10.1055/s-0033-1338642
DOI: 10.1055/s-0033-1338642
special topic
Utilization of a Copper on Iron Catalyst for the Synthesis of Biaryl Systems and Benzoxazines via Oxidative Arylation of Anilide Derivatives
Weitere Informationen
Publikationsverlauf
Received: 28. Februar 2014
Accepted after revision: 13. April 2014
Publikationsdatum:
28. Mai 2014 (online)


Abstract
Heterogeneous copper on iron catalyst serves as an efficient alternative copper source for arylation reactions using hypervalent iodonium salts. The copper(0) catalyst affords meta-arylation of pivalanilides, while 2-ethynylanilides undergo oxidative carboarylation–ring closure with diaryliodonium salts.
Supporting Information
- for this article is available online at http://www.thieme-connect.com/products/ejournals/journal/ 10.1055/s-00000084.
- Supporting Information