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DOI: 10.1055/s-0033-1338625
Recent Advances in Palladium-Catalyzed C(sp3)–H Activation for the Formation of Carbon–Carbon and Carbon–Heteroatom Bonds
Publikationsverlauf
Received: 17. Dezember 2013
Accepted after revision: 16. Januar 2014
Publikationsdatum:
30. April 2014 (online)
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Abstract
Within this review, recent developments in the field of C(sp3)–H activation catalyzed by palladium are discussed. Both intra- and intermolecular reactions towards carbon–carbon and carbon–heteroatom bonds are covered. In the case of intramolecular reactions, asymmetric versions are reported as well. The main focus of this review is literature of the last five years until late 2013.
1 Introduction
2 Intramolecular C(sp3)–H Activation
2.1 Carbon–Carbon Coupling
2.2 Carbon–Heteroatom Coupling
2.3 Stereoselective Reactions
3 Intermolecular C(sp3)–H Activation
3.1 Carbon–Carbon Coupling
3.2 Carbon–Heteroatom Coupling
4 Conclusion and Outlook
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For recent reviews on various aspects of C–H activation, see:
For reviews dedicated to sp2 C–H activation, see:
For reviews on sp3 C–H activation, see:
For examples, see: