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Synlett 2013; 24(3): 347-350
DOI: 10.1055/s-0032-1318110
DOI: 10.1055/s-0032-1318110
letter
Mechanistic Insights into Palladium Leaching in Novel Pd/C-Catalyzed Boron-Heck Reaction of Arylboronic Acid
Further Information
Publication History
Received: 12 November 2012
Accepted after revision: 30 December 2012
Publication Date:
23 January 2013 (online)
Abstract
For the first time, Pd/C has been used for the Boron-Heck reaction, and the detailed mechanistic aspects of the reaction have been proven experimentally by a leaching test as well as by cyclic voltammetry studies. The results indicate that palladium leaching as a Pd(II) species, by oxidative addition of the arylboronic acid, is responsible for the reaction.
Key words
heterogeneous catalysis - Pd/C - arylboronic acids - palladium leaching - Boron-Heck reactionSupporting Information
- for this article is available online at http://www.thieme-connect.com/ejournals/toc/synlett.
- Supporting Information
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References and Notes
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