Synthesis 2013; 45(10): 1380-1386
DOI: 10.1055/s-0032-1316908
paper
© Georg Thieme Verlag Stuttgart · New York

Synthesis of Iminonitriles by Oxone/TBAB-Mediated One-Pot Oxidative Three-Component Strecker Reaction

Jean-Baptiste Gualtierotti
Institute of Chemical Sciences and Engineering, Ecole Polytechnique Fédérale de Lausanne, EPFL-SB-ISIC-LSPN, BCH 5304, 1015 Lausanne, Switzerland    Fax: +41(21)6939740   Email: jieping.zhu@epfl.ch
,
Xavier Schumacher
Institute of Chemical Sciences and Engineering, Ecole Polytechnique Fédérale de Lausanne, EPFL-SB-ISIC-LSPN, BCH 5304, 1015 Lausanne, Switzerland    Fax: +41(21)6939740   Email: jieping.zhu@epfl.ch
,
Qian Wang
Institute of Chemical Sciences and Engineering, Ecole Polytechnique Fédérale de Lausanne, EPFL-SB-ISIC-LSPN, BCH 5304, 1015 Lausanne, Switzerland    Fax: +41(21)6939740   Email: jieping.zhu@epfl.ch
,
Jieping Zhu*
Institute of Chemical Sciences and Engineering, Ecole Polytechnique Fédérale de Lausanne, EPFL-SB-ISIC-LSPN, BCH 5304, 1015 Lausanne, Switzerland    Fax: +41(21)6939740   Email: jieping.zhu@epfl.ch
› Author Affiliations
Further Information

Publication History

Received: 18 March 2013

Accepted after revision: 20 March 2013

Publication Date:
08 April 2013 (online)


Abstract

Oxidative three-component reaction of aldehydes, amines, and TMSCN in a biphasic solvent system (toluene/H2O) containing Oxone, tetra-n-butylammonium bromide (TBAB) and sodium bicarbonate afforded α-iminonitriles in good to excellent yields. This oxidative Strecker reaction was applicable to a wide range of aldehydes and amines, aromatic or aliphatic, of different electronic and steric properties. Substituted 1-aza-2-cyano-1,3-dienes were also accessible using α,β-unsaturated aldehydes as inputs.

Supporting Information

 
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