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Synlett 2012; 23(10): 1446-1458
DOI: 10.1055/s-0031-1290967
DOI: 10.1055/s-0031-1290967
account
Method in the Madness – Methodology from Total Synthesis
Weitere Informationen
Publikationsverlauf
Received: 17. Dezember 2011
Accepted after revision: 11. Januar 2012
Publikationsdatum:
29. Mai 2012 (online)


Abstract
A review surveying the synthetic methodology developed by the Williams group over the last ten years, driven by natural product total synthesis, is presented. An underlying theme over this time has been the reliance on physical organic chemistry, organometallics and the cyclohexane ring system.
1 Introduction
2 Morita–Baylis–Hilman (MBH) Reaction
3 2-Iodoxybenzoic Acid (IBX)
4 Wittig Reagents
5 cis-Alkenes for 6π-Electrocyclisations
6 Ketal-Claisen Rearrangements
7 Silver(I) Acetylides
8 Photochemistry
9 Acyl Anion Equivalents
10 Conclusion