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Synlett 2012; 23(18): 2657-2662
DOI: 10.1055/s-0031-1290465
DOI: 10.1055/s-0031-1290465
letter
Palladium-Catalyzed Cyclization of Cyclopropyl-Substituted 1,6-Enynes to 5.7-Bicyclic Trienes or Monocyclic Trienes Depending upon the Leaving Group
Weitere Informationen
Publikationsverlauf
Received: 26. Juli 2012
Accepted after revision: 15. August 2012
Publikationsdatum:
21. September 2012 (online)
![](https://www.thieme-connect.de/media/synlett/201218/lookinside/thumbnails/10.1055-s-0031-1290465-1.jpg)
Abstract
Palladium-catalyzed cyclization of cyclopropyl-substituted 1,6-enynes proceeded in two ways depending on the presence or absence of a leaving group. In the presence of the leaving group, 5.7-bicyclic trienes were obtained as the sole products; in the absence of the leaving group, monocyclic trienes were isolated.
Supporting Information
- for this article is available online at http://www.thieme-connect.com/ejournals/toc/synlett.
- Supporting Information
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References and Notes
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For reviews, see:
For a review, see:
For Ru, see:
For Rh, see:
In some transition-metal-catalyzed reactions, the presence of carbon monoxide was helpful to the reaction even though the reaction was not related to the carbonylation, see: