Abstract
The nickel-catalyzed borylation of aryl halides with 5-(tert -butyldimethylsiloxymethyl)-5-methyl-1,3,2-dioxaborinane,
prepared in situ, was achieved. The mild reaction conditions allowed
common functional groups in the aryl halides to be tolerated. The
products of this borylation are potential precursors of aryl triolborates.
Key words
carbon-boron bond formation - nickel catalysis - cross-coupling - aryl halides - hydroboranes
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