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Synthesis 2012(4): 575-578
DOI: 10.1055/s-0031-1289669
DOI: 10.1055/s-0031-1289669
PAPER
© Georg Thieme Verlag
Stuttgart ˙ New York
Specific Polar Solvents as Organocatalysts for the Hydrosilylation of Isoprene
Further Information
Received
9 September 2011
Publication Date:
16 January 2012 (online)
Publication History
Publication Date:
16 January 2012 (online)
Abstract
Isoprene was hydrosilylated in the absence of transition metals by using specific organic solvents as both reaction media and organocatalysts. A highly selective reaction with successful catalyst recycling could be performed by using propylene carbonate as the reaction medium.
Key words
hydrosilylations - homogeneous catalysis - solvent effects - dienes - silanes
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