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Synthesis 2012(2): 259-264  
DOI: 10.1055/s-0031-1289617
PAPER
© Georg Thieme Verlag Stuttgart ˙ New York

Synthesis of Diamondoid Carboxylic Acids

Natalie A. Fokinaa, Boryslav A. Tkachenkoa, Jeremy E. P. Dahlb, Robert M. K. Carlsonb, Andrey A. Fokin*a,c, Peter R. Schreiner*a
a Institute of Organic Chemistry, Justus-Liebig University, Heinrich-Buff-Ring 58, 35392 Giessen, Germany
Fax: +49(641)9934309; e-Mail: prs@org.chemie.uni-giessen.de;
b Stanford University, Stanford Institute for Materials & Energy Science, 476 Lomita Mall, Stanford, CA 94305, USA
c Department of Organic Chemistry, Kiev Polytechnic Institute, pr. Pobedy 37, 03056 Kiev, Ukraine
e-Mail: aaf@xtf.ntu-kpi.kiev.ua;
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Publikationsverlauf

Received 21 October 2011
Publikationsdatum:
23. November 2011 (online)

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Abstract

Procedures for the synthesis of apical mono-, di-, and tricarboxylic acids of triamantane, [121]tetramantane, and [1(2,3)4]pentamantane, apical diacetic acids of diamantane and triamantane, as well as medial propionic acids of diamantane and triamantane were elaborated starting from the corresponding alcohols and bromides. The obtained diamondoid acids were characterized as their methyl ester derivatives.

Key words

bromides - carboxylic acids - diamondoids - esters - hydrocarbons - nanostructures

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