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Synthesis 2012(2): 259-264
DOI: 10.1055/s-0031-1289617
DOI: 10.1055/s-0031-1289617
PAPER
© Georg Thieme Verlag
Stuttgart ˙ New York
Synthesis of Diamondoid Carboxylic Acids
Further Information
Received
21 October 2011
Publication Date:
23 November 2011 (online)
Publication History
Publication Date:
23 November 2011 (online)
![](https://www.thieme-connect.de/media/synthesis/201202/lookinside/thumbnails/10.1055-s-0031-1289617-1.jpg)
Abstract
Procedures for the synthesis of apical mono-, di-, and tricarboxylic acids of triamantane, [121]tetramantane, and [1(2,3)4]pentamantane, apical diacetic acids of diamantane and triamantane, as well as medial propionic acids of diamantane and triamantane were elaborated starting from the corresponding alcohols and bromides. The obtained diamondoid acids were characterized as their methyl ester derivatives.
Key words
bromides - carboxylic acids - diamondoids - esters - hydrocarbons - nanostructures
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