Homogeneous Silver(I) Salts
and Heterogeneous Ag3PW12O40-Catalyzed Intermolecular
Allylation of Arenes with Allylic Alcohols

Guo-Qiang Chen; Zhen-Jiang Xu; Sharon Lai-Fung Chan; Cong-Ying Zhou; Chi-Ming Che

doi:10.1055/s-0031-1289548

LETTER

Homogeneous Silver(I) Salts and Heterogeneous Ag₃PW₁₂O₄₀-Catalyzed Intermolecular Allylation of Arenes with Allylic Alcohols

Guo-Qiang Chen^a, Zhen-Jiang Xu^a, Sharon Lai-Fung Chan^b, Cong-Ying Zhou^b, Chi-Ming Che*^a,b
^a Shanghai-Hong Kong Joint Laboratory in Chemical Synthesis, Shanghai Institute of Organic Chemistry, 345 Ling Ling Road, 200032 Shanghai, P. R. of China
^b Department of Chemistry, State Key Laboratory of Synthetic Chemistry, and Open Laboratory of Chemical Biology of the Institute of Molecular Technology for Drug Discovery and Synthesis, The University of Hong Kong, Pokfulam Road,Hong Kong, P. R. of China
Fax: +86(852)28571586; e-Mail: cmche@hku.hk;

Abstract

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Abstract

AgOTf is an effective catalyst for intermolecular allylation of aromatic and heteroaromatic compounds with allylic alcohols affording allylated arenes in up to 99% yields. Heterogeneous allylation of arenes catalyzed by Ag₃PW₁₂O₄₀ gave comparable product yields to those obtained by AgOTf. Ag₃PW₁₂O₄₀ could be reused five times with slightly decreased activity.

Key words

allylation - allylic alcohols - silver catalysis - Friedel-Crafts alkylation - recyclable

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Referenzen

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Zusatzmaterial

Supporting Information

Homogeneous Silver(I) Salts and Heterogeneous Ag3PW12O40-Catalyzed Intermolecular Allylation of Arenes with Allylic Alcohols

Homogeneous Silver(I) Salts and Heterogeneous Ag₃PW₁₂O₄₀-Catalyzed Intermolecular Allylation of Arenes with Allylic Alcohols