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Synfacts 2011(11): 1231-1231
DOI: 10.1055/s-0031-1289193
DOI: 10.1055/s-0031-1289193
Metal-Mediated Synthesis
© Georg Thieme Verlag
Stuttgart ˙ New York
Synthesis of Multialkylated Olefins through Carbozirconation and Coupling
Y. Nishihara*, Y. Okada, J. Jiao, M. Suetsugu, M.-T. Lan, M. Kinoshita, M. Iwasaki, K. Takagi
Okayama University, Japan
Further Information
Publication History
Publication Date:
19 October 2011 (online)
Significance
The authors describe a new procedure for the formation of tri- and tetrasubstituted olefins by carbozirconation of 1-alkynylboronates and successive Negishi and/or Suzuki-Miyaura cross-coupling with high regio- and stereoselectivities.