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Synlett 2011(13): 1816-1820
DOI: 10.1055/s-0030-1260964
DOI: 10.1055/s-0030-1260964
LETTER
© Georg Thieme Verlag
Stuttgart ˙ New York
Allyl and Benzyl Dance under Basic Conditions
Weitere Informationen
Received
9 May 2011
Publikationsdatum:
21. Juli 2011 (online)
Publikationsverlauf
Publikationsdatum:
21. Juli 2011 (online)
![](https://www.thieme-connect.de/media/synlett/201113/lookinside/thumbnails/10.1055-s-0030-1260964-1.jpg)
Abstract
Ugi-Smiles adducts formed from allyl (propargyl or benzyl) amine rearrange under basic condition with an allyl migration between two nitrogen atoms. The shift is reversible and may be controlled by the strength of the base used in the reaction.
Key words
Ugi-Smiles - isocyanide - multicomponent couplings - allyl - benzyl - propargyl - migration
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