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Synfacts 2011(6): 0688-0688
DOI: 10.1055/s-0030-1260377
DOI: 10.1055/s-0030-1260377
Polymer-Supported Synthesis
© Georg Thieme Verlag
Stuttgart ˙ New York
Recyclable Polystyrene-Supported (Dichloroiodo)benzene
J.-M. Chen, X.-M. Zeng, K. Middleton, V. V. Zhdankin*
University of Minnesota Duluth, USA and Jiaxing University, P. R. of China
Weitere Informationen
Publikationsverlauf
Publikationsdatum:
19. Mai 2011 (online)
![](https://www.thieme-connect.de/media/synfacts/201106/lookinside/thumbnails/10.1055-s-0030-1260377-1.jpg)
Significance
Herein, a one-pot preparation of polystyrene-supported (dichloroiodo)benzene (PS-DCIB) from polystyrene, iodine, and sodium hypochlorite (a commercial bleach) is described. The chlorination of alkenes, arenes, and a 1,3-di-ketone as well as the oxidation of alcohols with a stoichiometric amount of PS-DCIB were carried out to give the corresponding chloro compounds (72-85% yield) and carbonyl compounds (20-92% yield), respectively.