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Synthesis 2011(22): 3581-3591
DOI: 10.1055/s-0030-1260240
DOI: 10.1055/s-0030-1260240
REVIEW
© Georg Thieme Verlag
Stuttgart ˙ New York
Heck Arylations of Baylis-Hillman Adducts
Further Information
Received
26 July 2011
Publication Date:
26 September 2011 (online)
Publication History
Publication Date:
26 September 2011 (online)
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Abstract
This short review examines the palladium-catalyzed arylation of the C=C bond of Baylis-Hillman adducts. It summarizes the different intermolecular and intramolecular reaction procedures, and contains detailed tables making it easier to compare their efficiency.
1 Introduction
2 Intermolecular Reactions
2.1 Without Decarboxylation
2.2 With Decarboxylation
3 Intramolecular Reactions
4 Conclusions
Key words
catalysis - palladium - Heck arylation - Baylis-Hillman - cyclization - decarboxylation
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