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Synthesis 2011(14): 2297-2302
DOI: 10.1055/s-0030-1260078
DOI: 10.1055/s-0030-1260078
PAPER
© Georg Thieme Verlag
Stuttgart ˙ New York
An Efficient Copper(I) Iodide Catalyzed Synthesis of Diaryl Selenides through CAr-Se Bond Formation Using Solvent Acetonitrile as Ligand
Further Information
Received
21 March 2011
Publication Date:
17 June 2011 (online)
Publication History
Publication Date:
17 June 2011 (online)
![](https://www.thieme-connect.de/media/synthesis/201114/lookinside/thumbnails/10.1055-s-0030-1260078-1.jpg)
Abstract
A wide range of diaryl selenides can be synthesized through CAr-Se bond formation using readily available copper(I) iodide as catalyst under mild reaction conditions (82 ˚C) from aryl iodides and diphenyl diselenide. In this coupling reaction, solvent acetonitrile acts as ligand for copper(I) iodide and no external ligand is required. Less reactive aryl bromides also provide the diaryl selenides in good isolated yields.
Key words
copper catalyst - acetonitrile - C-Se bond formation - selenium
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