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Synthesis 2011(11): 1717-1722
DOI: 10.1055/s-0030-1260043
DOI: 10.1055/s-0030-1260043
PAPER
© Georg Thieme Verlag
Stuttgart ˙ New York
Facile and Quantitative Synthesis of 1,3-Diazaheterocycle-Fused 1,2,3-Triazole Derivatives Using Fluoroalkanesulfonyl Azide as a Diazo Transfer Reagent
Further Information
Received
28 February 2011
Publication Date:
13 May 2011 (online)
Publication History
Publication Date:
13 May 2011 (online)
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Abstract
A series of 1,3-diazaheterocycle-fused 1,2,3-triazoles were conveniently and quantitatively prepared by 1,3-dipolar cycloaddition of heterocyclic ketene aminals with fluoroalkanesulfonyl azide, followed by elimination of fluoroalkanesulfonyl amide at room temperature without any catalyst.
Key words
fluoroalkanesulfonyl azide - ketene aminals - 1,3-dipolar cycloaddition - heterocycles - 1,3-diazaheterocycle-fused 1,2,3-triazole
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