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Synfacts 2010(12): 1383-1383
DOI: 10.1055/s-0030-1258865
DOI: 10.1055/s-0030-1258865
Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions
© Georg Thieme Verlag
Stuttgart ˙ New York
Gold(I)-Catalyzed Diastereoselective Pyrrolidine Synthesis
M.-C. P. Yeh*, M.-N. Lin, W.-J. Chang, J.-L. Liou, Y.-F. Shih
National Taiwan Normal University, Taipei, Taiwan
Weitere Informationen
Publikationsverlauf
Publikationsdatum:
22. November 2010 (online)
Significance
The authors report a completely diastereoselective gold(I)-catalyzed cyclization to form cis-3-acyl-4-alkyenylpyrrolidines. Pyrrolidine products were formed in very nice yields, and this methodology can be extended to cyclopentane derivatives as well.