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Synfacts 2010(9): 1086-1086
DOI: 10.1055/s-0030-1257981
DOI: 10.1055/s-0030-1257981
Polymer-Supported Synthesis
© Georg Thieme Verlag
Stuttgart ˙ New York
Hydrogenation of Aromatics Catalyzed by Ruthenium(0) Nanoclusters
M. Zahmakiran, Y. Tonbul, S. Özkar*
Middle East Technical University, Ankara, Turkey
Weitere Informationen
Publikationsverlauf
Publikationsdatum:
23. August 2010 (online)
Significance
Ruthenium(0) nanoclusters supported on hydroxyapatite (Ru(0)/HAP) were prepared via treatment of RuCl3˙H2O with hydroxyapatite (HAP) followed by NaBH4 reduction. Ru(0)/HAP catalyzed the hydrogenation of aromatics in cyclohexane under 42 psi initial pressure of molecular hydrogen to give the corresponding cyclohexane derivatives with TOF values of 300-705 h-¹.