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Synfacts 2010(7): 0816-0816
DOI: 10.1055/s-0029-1220038
DOI: 10.1055/s-0029-1220038
Metal-Mediated Synthesis
© Georg Thieme Verlag
Stuttgart ˙ New York
Base-Free Aryl Coupling of Diazonium Compounds and Boronic Esters
H. Bonin, D. Delbrayelle, P. Demonchaux, E. Gras*
Université Paul Sabatier, Toulouse, Minakem, Beuvry-La-Forêt and Université de Toulouse, France
Weitere Informationen
Publikationsverlauf
Publikationsdatum:
22. Juni 2010 (online)
Significance
The authors report an unprecedented application of self-activated boronic esters in a base-free cross-coupling reaction with diazonium salts under mild and user-friendly conditions. The protocol tolerates a wide range of functional groups and affords unsymmetrical biaryls in high yields.